Viktor S. Camara, Marcio Hayashi, Alex S. Moraes, Pedro H. O. Santiago, Javier Ellena, Marco A. B. Ferreira, Antonio C. B. Burtoloso,

Abstract

The reaction of ketosulfoxonium ylides and allylic carbocations is described. Depending on the nature of the sulfoxonium ylide employed, highly substituted cyclopropanes or α-alkylated sulfoxonium ylides are obtained.

Links

https://doi.org/10.1039/d5qo01425e

BibTex

@article{Camara_2026, title={Reactions of ketosulfoxonium ylides with allylic carbocations: stereoselective and direct access to highly-substituted cyclo-propanes and α-alkylated ylides}, volume={13}, ISSN={2052-4129}, url={http://dx.doi.org/10.1039/d5qo01425e}, DOI={10.1039/d5qo01425e}, number={2}, journal={Organic Chemistry Frontiers}, publisher={Royal Society of Chemistry (RSC)}, author={Camara, Viktor S. and Hayashi, Marcio and Moraes, Alex S. and Santiago, Pedro H. O. and Ellena, Javier and Ferreira, Marco A. B. and Burtoloso, Antonio C. B.}, year={2026}, pages={584–596} }